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in contact for several more days before finally separating . news of the encounter was conveyed back to france , but the country was at this time in one of the most turbulent eras of the ongoing revolution and little notice was taken of events in india . historian william james notes that under normal political circumstances the action would have had more significant ram ##ification ##s , while edward pe ##lham brent ##on claims that the french deliberately ignored the report out of fear of ant ##ago ##nis ##ing britain . in britain , the admiralty approved of cornwall ##is ' actions , suggesting that the french were deliberately using the guise of trade to support mysore against britain . the action had no effect
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on the ongoing war in india , which was now centred on the inland city of ser ##inga ##pa ##tam . as british forces closed on the city in february 1792 , the tip ##u sultan initiated peace talks which brought the war to an end in exchange for concessions to the company and its indian allies . = loose ( nelly fur ##tad ##o album ) = loose is the third studio album by canadian singer and songwriter nelly fur ##tad ##o , released on 6 june 2006 by ge ##ffen records and the mo ##sley music group . following the release of fur ##tad ##o ' s second album , folklore ( 2003 ) through dream ##works records , it was announced that universal
| 75 |
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music group would acquire dream ##works records , the later was folded into the inter ##scope ge ##ffen a & m umbrella where fur ##tad ##o would release any new music . tim ##bala ##nd and his protege dan ##ja produced the bulk of the album , which incorporates influences of dance , r & b and hip hop . the album explores the theme of female sexuality and has been described as intro ##sp ##ect ##ive or even sad in parts . the album received criticism because of the sexual image fur ##tad ##o adopted for the recording , as some critics felt it was a pl ##oy to sell more records . further controversy rose over accusations of pl ##agi ##aris ##m on tim
| 814 |
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| 922 |
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supported by the get loose tour , which is the subject of the concert dvd loose : the concert . " loose " debuted at number one , making it fur ##tad ##o ' s first album to top the chart along with eight singles were released from the album , including the us number @ - @ one singles " prom ##is ##cu ##ous " and " say it right " , which received grammy award nominations for best pop collaboration with vocals and best female pop vocal performance , respectively . other successful singles include the uk number @ - @ one single " mane ##ater " and the european number one single " all good things ( come to an end ) "
| 923 |
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. = = background = = fur ##tad ##o ' s second album , folklore , was released in november 2003 . the lead single is " powerless ( say what you want ) " and the second single is the ballad " try " . the album was not as successful as her debut , partly due to the album ' s less " poppy " sound . " powerless ( say what you want ) " was later remixed , featuring colombian rocker juan ##es , who had previously worked with fur ##tad ##o on his track " f ##oto ##gra ##fia " ( " photograph " ) . the two would collaborate again on " te bus ##que " ( " i searched
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for you " ) , the single from fur ##tad ##o ' s album loose . the album was under ##pro ##mot ##ed from her label dream ##works records ; it was announced on 11 november 2003 that universal music group reached an agreement to acquire dream ##works records from dream ##works sk ##g for " about $ 100 million " . the purchase came at a time when the music business was " going through major changes " as it struggled to " counter falling sales and the impact of unofficial online music sales " . dream ##works records was folded into the inter ##scope ge ##ffen a & m umbrella label in january 2004 . fur ##tad ##o ' s recording contract was then
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absorbed into ge ##ffen records . = = recording = = fur ##tad ##o began work on loose by holding with em ##ce ##e jelly ##stone what she referred to as a " hip @ - @ hop workshop " , in which they would " write rhymes , di ##sse ##ct them , and try different flows over beats . " the first producers she worked with were track & field — who co @ - @ produced her first two albums , whoa , nelly ! ( 2000 ) and folklore ( 2003 ) — and by may 2005 , she had collaborated with swollen members and k ' na ##an . she worked with nell ##ee hooper in london on reggae @ -
| 905 |
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@ oriented material and with lester mendez in los angeles on acoustic songs . one of the tracks mendez helped to create is " te bus ##que " , which is co @ - @ written by and features juan ##es , who collaborated with fur ##tad ##o on his 2002 song " f ##oto ##gra ##fia " . during her time in los angeles , she worked with rick now ##els , who co @ - @ wrote and produced " in god ' s hands " and " somebody to love " . in miami , florida , fur ##tad ##o collaborated with ph ##ar ##rell ( who introduced her to reggae ##ton and who gave her a " shout @ - @ out
| 109 |
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] | 1,411 |
" in his 2005 single " can i have it like that " ) and scott st ##or ##ch ( with whom she recorded a " straight @ - @ up rap song " ) before entering the studio with tim ##bala ##nd . he and his protege at the time , dan ##ja , co @ - @ produced eight of the tracks , with another produced solely by dan ##ja . for some of the beats on the songs , tim ##bala ##nd finished work on ones already present in the studio that were half @ - @ developed or just " nucleus ##es " ; the rest were completely reworked . fur ##tad ##o recorded around forty tracks for loose , deciding which
| 811 |
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] | 1,412 |
she would include based on the sonic ##s of the album — she called tim ##bala ##nd " a sonic extra ##ter ##rest ##rial " who came up with a sequence of songs that flowed , and said that the one she had devised was supposedly un ##sat ##is ##factory . she recorded an unreleased collaboration with justin timber ##lake , " crowd control " , which she described as " kind of sexy " and " a cute , club ##by , upbeat , fun track " . other songs considered for inclusion on the album include " chill boy " , " friend of mine " , " go " , " hands in the air " , " pretty boy " , "
| 811 |
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] | 1,413 |
vice " and " weak " . fur ##tad ##o said in her diary on her official website that she recorded a remix of " mane ##ater " with rapper lil wayne ; it was only released as part of a compilation album , tim ##bala ##nd ' s remix & soundtrack collection , she also used the instrumental of the song during many television performances of " mane ##ater " . a version of " all good things ( come to an end ) " featuring vocals by cold ##play lead singer chris martin , who co @ - @ wrote the song , was not released after a request from martin ' s label , emi . the song was released on the album
| 893 |
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] | 1,414 |
, but only fur ##tad ##o ' s vocals are featured . fur ##tad ##o explained that " loose was 90 percent written with a beat first , and then i ’ d write my melodies and songs to the beat . " the " off @ - @ the @ - @ cuff " conclusion to production was one of the reasons the album was titled loose . it was named partly after the spontaneous decisions she made when creating the album . the album is also called loose because it is " the opposite of calculated " and came naturally to fur ##tad ##o and tim ##bala ##nd ; she called him her " distant musical cousin because he was always pushing boundaries and
| 811 |
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] | 1,415 |
always carving out his own path " , which she believed she was doing with loose . " i think you have to keep surprising people as an artist , and i like that — i love doing that " , she said . loose was also named partly for the r & b girl group t ##lc , who fur ##tad ##o said she admire ##s for " taking back their sexuality , showing they were complete women . " she said she wanted the album to be " assert ##ive and cool " and " sexy but fun " , like t ##lc , mc l ##yte , queen la ##ti ##fa ##h and janet jackson , who inspired fur ##tad ##o because ,
| 821 |
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] | 1,416 |
as she put it , she was " comfortable in her sexuality and woman ##hood " when her 1993 single " that ' s the way love goes " was released . during the recording of loose , fur ##tad ##o listened to several electro and rock musicians , including bloc party , system of a down , m . i . a . , fei ##st , queens of the stone age , metric and death from above 1979 , some of whom influenced the " rock sound " present on the album and the " coughing , laughing , distorted bass ##lines " that were kept in the songs deliberately . according to her , music by such bands is " very loud and
| 806 |
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] | 1,417 |
has a garage theme " to it , some of which she felt she captured on the album . fur ##tad ##o has said rock music is " rhythmic again " and hip hop @ - @ influenced after it had become " so churning and boring . " because the mixing engineers were aware of tim ##bala ##nd and fur ##tad ##o ' s rock influences , the songs were mixed on a mixing board in the studio instead of " the fancy mixer at the end " . fur ##tad ##o said she preferred the louder volume that process gave to the album because she wanted it to sound like her demo tapes , which she prefers to her finished albums . she said
| 905 |
[
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] | 1,418 |
, " it didn ' t have that final wash over it ; it didn ' t have the final pressing at the end , save for a couple sounds " . = = music and lyrics = = fur ##tad ##o said that with the release of her albums before loose , she had wanted to prove herself as a musician and earn respect from listeners through using many different instruments on an album , which most hip hop musicians did not do . after she believed she had accomplished that , she felt she had freedom to make the type of music she " really love [ d ] " . fur ##tad ##o said her previous problem with hip hop was that she
| 891 |
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did not think it was good enough to base one of her albums on , but that she then asked herself why she was being " pre ##ten ##tious " . the album represents her separating from such notions and , in her words , " jumping in the deep end of the pool — ' ah ##h , screw it , this is fun ! ' " . fur ##tad ##o said she considers herself " all over the map " and prom ##is ##cu ##ous musically because she is not faithful to one style . for the first time , fur ##tad ##o worked with a variety of record producers and followed a more collaborative approach in creating the album . produced primarily by
| 821 |
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tim ##bala ##nd and dan ##ja , loose showcases fur ##tad ##o experimenting with a more r & b – hip hop sound and , as she put it , the " surreal , theatrical elements of ' 80s music " . she has categorized the album ' s sound as punk @ - @ hop , which she describes as eu ##ry ##th ##mics @ - @ influenced " modern , poppy , sp ##ook ##y music " and stated that " there ' s a mysterious , after @ - @ midnight vibe to [ it ] that ' s extremely vis ##cera ##l " . fur ##tad ##o has described the album as " more urban , more american , more hip @
| 823 |
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- @ hop , [ and ] more simplified " than her earlier work , which she said was more layered and texture ##d because she " tend [ s ] to over ##thi ##nk things " . in contrast , during her studio time with tim ##bala ##nd , she said she was " in the vip boys club of just letting go " and being more imp ##ulsive . according to fur ##tad ##o , instead of " pristine stuff " , the album features " really raw " elements such as distorted bass lines , laughter from studio outta ##kes and general " room for error " . fur ##tad ##o has said loose is not as much about the lyrics , which
| 792 |
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are not included in the liner notes , as it is about " ind ##ul ##ging in pleasures — whether it ' s dancing or love ##making . " according to her , she wasn ' t trying to be sexy with the album — " i think i just am sexy now " , she said . the opening track , " afraid " ( featuring rapper attitude ) , is a description of fur ##tad ##o ' s fear of what people think of her , and she has said the chorus reminds her of " walking down the hall in high school . . . because you live from the outside in . now that i ' m an adult , i care
| 821 |
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about the inside of me . . . before i said i didn ' t care about what people thought about me , but i really did . " " mane ##ater " is an up ##tem ##po electro rock song that combines 1980s electro synth ##s and a more dance @ - @ oriented beat . the up @ - @ tempo song has prominent electro ##pop and synth ##pop influences and is lyrical ##ly related to how people become " hot on themselves " when dancing in their underwear in front of a mirror . " prom ##is ##cu ##ous " ( featuring tim ##bala ##nd ) was inspired by a flirting exchange fur ##tad ##o had with attitude , who co @ -
| 894 |
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@ wrote the song she has characterised the fifth track , " showtime " , as " a proper r & b slow jam " . " no hay i ##gua ##l " is a hip hop and reggae ##ton song , that has a span ##gli ##sh tongue twist ##er over " future @ - @ tr ##op ##ic " beats . the song contains a " sharp mix " of percussion and " empowered chanting " . in " no hay i ##gua ##l " , fur ##tad ##o sings in spanish and rap ##s in portuguese over a reggae ##ton rhythm . the album also features more intro ##sp ##ect ##ive songs , and the sunday times wrote that it " has a
| 102 |
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surprising sadness to it . " the seventh track , " te bus ##que " , which features latin singer juan ##es , is about fur ##tad ##o ' s experiences with depression , which she said she has had periodically since she was around seventeen years old . fur ##tad ##o said she was unsure what " say it right " is about , but that it en ##cap ##sul ##ates her feeling when she wrote it and " taps into this other sphere " ; in an interview for the sunday times , it was mentioned that it is about her breakup with dj jasper ga ##hun ##ia , the father of her daughter . " in god ' s hands " , another
| 818 |
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song on the album , was also inspired by the end of their relationship . in april 2006 , a remix of " no hay i ##gua ##l " featuring call ##e 13 was issued as a club single in the us . during the same period , " prom ##is ##cu ##ous " ( featuring tim ##bala ##nd ) was released for digital download in north america . prom ##is ##cu ##ous became fur ##tad ##o ' s first single to top the us billboard hot 100 and was released in australia , where it reached the top five . the lead single in europe and latin america , " mane ##ater " , was released in late may to early june 2006 . it
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became fur ##tad ##o ' s first single to top the uk singles chart and made the top ten in other countries ; it reached the top five in germany and the top twenty in france and latin america . the second single in europe , " prom ##is ##cu ##ous " , was released in late august to early september 2006 but it did not perform as well as " mane ##ater " . it peaked inside the top five in the uk and the top ten in other countries , including germany , and it reached the top twenty in france . during the same period , " mane ##ater " began its run as the second single in north america ; it was
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not given a commercial release ) , and it reached the top five in australia . " all good things ( come to an end ) " reached number one on the pan @ - @ european singles chart and the top five in the uk , and it was the album ' s most successful single in germany , where it topped the chart , and in france , where it became a top ten hit . after the release of " say it right " in europe in march 2007 , the single reached the top five in germany and the top ten in the uk , where it was a download @ - @ only release . the video for " all good
| 923 |
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things ( come to an end ) " was released in north america during this period . " all good things ( come to an end ) " peaked in the top five in canada and in the top twenty in australia , though it only reached the lower half of the us hot 100 . the album ' s fifth and final uk single was " in god ' s hands " , and the fifth and final single in north america was " do it " . in may 2007 , fur ##tad ##o mentioned the possibility of a sixth or seventh single , mentioning the examples of nickel ##back ' s all the right reasons and the pussy ##cat dolls ' pc ##d
| 710 |
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as albums that were being supported by seven singles at the time . fur ##tad ##o said she liked the possibility because she thought loose was good and " want [ ed ] people to hear as much of it as possible " before she took time off . two other songs , " te bus ##que " and " no hay i ##gua ##l " , were released as singles in other regions of the world . " te bus ##que " was the lead single in spain because of the limited success hip @ - @ hop / r & b @ - @ influenced songs in the style of " prom ##is ##cu ##ous " and " mane ##ater " achieved in the
| 923 |
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country . it was not released in the united states , but it was given airplay on latin music radio stations and reached the top forty on billboard ' s latin pop airplay chart . the " no hay i ##gua ##l " remix featuring call ##e 13 was released in latin america , and the music video debuted in september . = = release and promotion = = the album was first released in japan on 7 june 2006 through universal music group before being released two days later in germany . in the united kingdom loose was released on 12 june 2006 via ge ##ffen records and was released eight days later on 20 june 2006 in canada and the united states . in
| 924 |
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2007 the album was re @ - @ released in germany . the re @ - @ release included bonus content . during the promotion of loose , fur ##tad ##o performed at major music festivals and award shows . in europe , she appeared at rock am ring and rock @ - @ im @ - @ park in germany and the pink ##pop festival in the netherlands in june 2006 . she performed in canada at the calgary stampede , the ottawa blues ##fest in july , and at the o ##vation music festival in september . shortly after her august 2006 performance at the summer sonic in japan , she sang at the teen choice awards . in november , she contributed to
| 852 |
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the entertainment during the world music awards , the american music awards and the 94 ##th grey cup halftime show . she performed at the 2007 nr ##j music awards , held in january 2007 . fur ##tad ##o embarked on a world concert tour , the get loose tour , on 16 february 2007 in the uk , in support of the album ; the tour included thirty @ - @ one dates in europe and canada , with additional shows in the us , japan , australia and latin america . fur ##tad ##o described the show as a " full sensory experience " with " a beginning , middle and end . . . [ it ] takes you on a journey "
| 27 |
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, also stress ##ing the importance of crowd involvement and " sp ##ont ##ane ##ity and raw ##ness , because those are my roots , you know ? i started by doing club shows , and that ' s the energy i love , the raw club energy of just feeling like you ' re rocking out . " though fur ##tad ##o said choreographed dance routines were to be included in the show , she described it as " music @ - @ based . . . everything else is just to keep it sophisticated and sensual and fun . " fur ##tad ##o said she hoped to have chris martin , juan ##es , justin timber ##lake , tim ##bala ##nd and call ##e
| 822 |
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13 to guest on the tour , and have a " revolving door " of opening acts with latin musicians opening in the us . = = commercial performance = = loose debuted at number one on the canadian albums chart , selling more than 34 @ , @ 000 copies in its first week , at that time the year ' s strongest debut for a canadian artist . in late july , after fur ##tad ##o embarked on a short tour of canada and made a guest appearance on the television show canadian idol , the album returned to number one . it subsequently stayed near the top of the album chart until late january 2007 , when it reached number one again for
| 922 |
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two weeks . it was the third best @ - @ selling album of 2006 in canada , and the highest selling by a female solo artist , with 291 @ , @ 700 copies sold . the canadian recording industry association ( cr ##ia ) certified loose five times platinum in may 2007 for shipments of more than 500 @ , @ 000 copies . it stayed in the top twenty for fifty @ - @ seven weeks . the album debuted at number one on the us billboard 200 chart , making it fur ##tad ##o ' s first album to top the chart with first @ - @ week sales of 219 @ , @ 000 ; it was certified platinum by the
| 921 |
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recording industry association of america ( riaa ) and ranked sixty @ - @ fourth on the billboard 2006 year @ - @ end chart . loose exited the us top ten in august 2006 but re @ - @ entered it in march 2007 , and according to nielsen sounds ##can in october 2007 , it had sold two million units . the album ranked thirty @ - @ second on the billboard 2007 year @ - @ end chart . in the united kingdom , loose entered the albums chart at number five ; in its forty @ - @ third week , it reached number four , and it was certified double platinum for shipments to retailers of more than 600 @ ,
| 921 |
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@ 000 copies . as of july 2007 , it had sold roughly 82 ##7 @ , @ 000 copies in the uk . the record was certified two times platinum in australia for more than 140 @ , @ 000 units shipped ; it reached number four there and was placed forty @ - @ fourth on the australian australian recording industry association ( aria ) list of 2006 bestseller ##s . the album entered the chart in germany at number one , spent a record forty @ - @ nine weeks in the german top ten , and was certified five times platinum . loose reached number one on the european top 100 albums chart in early 2007 , spending ten non @ -
| 921 |
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@ consecutive weeks at number one . by march 2007 , it had been certified gold or platinum in twenty @ - @ five countries . according to a ge ##ffen records press release , loose had sold more than seven million copies by november 2007 . = = critical reception = = loose received generally positive reviews from music critics ; it holds an average score of 71 out of 100 at aggregate website metacritic . allmusic and music ##om ##h cited the " rev ##ital ##ising " effect of tim ##bala ##nd on fur ##tad ##o ' s music , and the guardian called it " slick , smart and surprising . " q found most of it to be " an in ##vent
| 921 |
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##ive , hip @ - @ hop @ - @ in ##fle ##cted delight . " ke ##le ##fa san ##ne ##h of the new york times wrote that " the music and the lyrics are mainly aimed at dance floors , and yet this album keeps reminding listeners that a dance floor is one of the most complicated places on earth . " in its review , allmusic wrote " it ' s on this final stretch of the album that the fur ##tad ##o and tim ##bala ##nd pairing seems like a genuine collaboration , staying true to the nelly of her first two albums , but given an adventurous production that helps open her songs up . . . tim ##bala ##nd has
| 894 |
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rev ##ital ##ized nelly fur ##tad ##o both creative ##ly and commercially with loose " . she won her first brit award — best international female — in 2007 . in a mixed review , nick cat ##ucci of the village voice felt that fur ##tad ##o " sauce ##s up a bit too lu ##rid ##ly " and lacks " chemistry " with tim ##bala ##nd , writing that loose " isn ' t a love child , but a bump @ - @ and @ - @ grind that never finds a groove " . vibe stated , " she loses herself in gwen stefan ##i – like post ##uring , as on “ glow , ” and ethnic fusion ##s like “ no
| 811 |
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hay i ##gua ##l ” or “ te bus ##que . " in his consumer guide for the village voice , robert christ ##gau gave the album a " b " and named it " du ##d of the month " , indicating " a bad record whose details rarely merit further thought . " christ ##gau viewed that its dance @ - @ oriented tracks " might accomplish god ' s great plan on the dance @ - @ floor . but as songs they ' re not much " . considerable attention was generated by the more sexual image of fur ##tad ##o presented in promotion and publicity for the album , and in particular the music videos for " prom ##is ##cu ##ous
| 894 |
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" and " mane ##ater " , in which she dances around with her mid ##ri ##ff exposed . according to maclean ' s magazine , some said that fur ##tad ##o ' s progression was a natural transformation of a pop singer ; others believed that she had " sold out " in an effort to garner record sales , particularly after her second album was a commercial failure in comparison to her first . maclean ' s wrote that her make ##over " seems a bit forced " and contrasted her with singers such as madonna and emily hai ##nes of metric : " [ they ] seem to be completely in control , even somewhat intimidating in their sexuality : they ' ve
| 888 |
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made a calculated decision for commercial and feminist reasons . in contrast , fur ##tad ##o ' s new , over ##t sexuality comes off as uno ##ri ##ginal — over ##don ##e by thousands of po ##ut ##y pop stars with a quarter of fur ##tad ##o ' s natural talent . . . the rev ##amp ##ing feels as if it ' s been imposed rather than chosen by the unique , art ##iculate singer we ' ve seen in the past . " dose magazine wrote that fur ##tad ##o ' s new " highly sexual ##ized " image was manufactured , and noted the involvement in the album ' s development of ge ##ffen ' s jimmy io ##vine , who helped
| 818 |
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to develop the pussy ##cat dolls , a girl group known for their sexually suggest ##ive dance routines . the writer also criticised fur ##tad ##o ' s discussion of her butt ##ocks and apparent rejection of feminism in a blend ##er magazine interview , writing : " girls , do you hear that churning ? those are the ideas of gloria stein ##em turning in their grave . " a writer for the canadian broadcasting corporation said that cy ##nic ##s could attribute fur ##tad ##o ' s commercial success with loose to her " amp ##ed @ - @ up sex appeal . " the writer added that , the failure of janet jackson ' s album dam ##ita jo ( 2004 ) indicated
| 796 |
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such a move was not in ##fall ##ible . fur ##tad ##o was " still dem ##ure compared to many of her competitors " — she avoided sporting linger ##ie or performing " christina ag ##uil ##era @ - @ style g ##yra ##tions or cal ##ist ##hen ##ics " in the " prom ##is ##cu ##ous " and " mane ##ater " videos . " despite its dramatic arrival . . . fur ##tad ##o ' s new image doesn ’ t feel calculated " , he said . " [ she ] seems to be thinking less and feeling more , to the benefit of her music . " in early 2007 , a video hosted on youtube led to reports that the song
| 704 |
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" do it " , and the tim ##bala ##nd @ - @ produced ring ##tone " block party " that inspired it , used — without authorization — the melody from finnish demos ##cene musician jan ##ne " tempest " sun ##i ' s song " acid ##ja ##zz ##ed evening " , winner of the assembly 2000 olds ##ko ##ol music competition . tim ##bala ##nd used the record of c ##64 adaptation of the song written by glenn rune gall ##ef ##oss ( gr ##g ) . tim ##bala ##nd admitted sampling the song , but said that he had no time to research its intellectual owner . han ##nu so ##rm ##une ##n , a finnish representative of universal which represents nelly
| 5 |
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fur ##tad ##o in finland , commented the controversy as follows in the 15 january 2007 issue of il ##tale ##ht ##i ; " in case that the artist decides to pursue the matter further , it ' s on him to go to america and confront them with the local use of law . it will require a considerable amount of faith and , of course , money . " on 9 february 2007 , tim ##bala ##nd commented on the issue in an mtv interview : " it makes me laugh . the part i don ' t understand , the dude is trying to act like i went to his house and took it from his computer . i don ' t know
| 822 |
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him from a can of paint . i ' m 15 years deep . that ' s how you attack a king ? you attack moi ? come on , man . you got to come correct . you the laughing stock . people are like , ' you can ' t be serious . ' " on 12 june 2009 , mi ##kko val ##ima ##ki , who is one of the legal counsel ##s of kernel records , the owner of the sound recording rights , reported that the case had been filed in florida . in january 2008 , turkish newspapers reported that kala ##n mu ##zi ##k , the record label that released turkish folk singer mu ##hli ##s aka ##rs ##u
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' s album ya dos ##t ya dos ##t , pressed charges against fur ##tad ##o for the loose track " wait for you " , which label officials said features the bag ##lam ##a instrumental part of aka ##rs ##u ' s song " allah allah des ##em gel ##se ##m . " = = track listing = = notes ^ a signifies a vocal producer = = personnel = = credits adapted from the loose liner notes . = = certification ##s = = = = release history = = the 2013 – 14 season was the 92 ##nd season of competitive association football and 77 ##th season in the football league played by york city football club , a professional football club based
| 85 |
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in york , north yorkshire , england . their 17th @ - @ place finish in 2012 – 13 meant it was their second consecutive season in league two . the season ran from 1 july 2013 to 30 june 2014 . nigel worth ##ington , starting his first full season as york manager , made eight permanent summer signing ##s . by the turn of the year york were only above the relegation zone on goal difference , before a 17 @ - @ match unbeaten run saw the team finish in seventh @ - @ place in the 24 @ - @ team 2013 – 14 football league two . this meant york qualified for the play @ - @ offs , and they
| 634 |
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were eliminated in the semi @ - @ final by fleetwood town . york were knocked out of the 2013 – 14 fa cup , football league cup and football league trophy in their opening round matches . 35 players made at least one appearance in nationally organised first @ - @ team competition , and there were 12 different goalscorer ##s . defender ben davies missed only five of the fifty @ - @ two competitive matches played over the season . wes fletcher finished as leading scorer with 13 goals , of which 10 came in league competition and three came in the fa cup . the winner of the club ##man of the year award , voted for by the club ' s
| 657 |
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| 634 |
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red ##bridge on the final day of the season . york finished the season in 17th @ - @ place in the 2012 – 13 league two table . following the previous season ' s conclusion lee bullock , jon cha ##llin ##or , chris doi ##g , ben ever ##son , scott kerr , david mc ##dai ##d , patrick mclaughlin , michael pot ##ts , jamie reed and jason walker were released by york , while matt ##y blair departed for fleetwood town . david mc ##gur ##k , lan ##re o ##ye ##ban ##jo , danny par ##slow , tom platt and chris smith signed new contracts with the club . new players signed ahead of the start of the season were goalkeeper
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| 684 |
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socks . the away kit included light blue shirts with white sleeves , white shorts and light blue socks . ben ##end ##en health continued as shirt sponsors for the second successive season . york began the season with a 1 – 0 home win over the previous season ' s play @ - @ off finalists , northampton town , with debut ##ant jarvis scoring the winning goal in the 90 ##th @ - @ minute . however , defeat came in york ' s match against championship side burnley in the first round of the league cup , going down 4 – 0 at home . the team endured their first league defeat of the season in the following game after being beaten 2
| 654 |
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– 0 away by da ##gen ##ham & red ##bridge , the home team scoring in each half . york then held hart ##le ##pool united to a 0 – 0 home draw , before being beaten 3 – 2 away by bristol rovers , in which jarvis scored twice before john @ - @ joe o ' tool ##e scored the winning goal for the home team in the 67 ##th @ - @ minute . two signing ##s were made shortly before the transfer deadline ; defender george taft was signed on a one @ - @ month loan from leicester city , while middlesbrough midfielder ryan bro ##bbe ##l joined on a one @ - @ month loan . midfielder john mc ##rea
| 654 |
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##dy , who had been told he had no future with the club , departed after signing for fc halifax town . jarvis gave york the lead away at exeter city before alan go ##w scored in each half to see the home team win 2 – 1 . york suffered their first home league defeat of the season after afc wimbledon won 2 – 0 , with michael smith scoring in each half . former ipswich town midfielder josh carson , who had a spell on loan with york the previous season , signed a contract until the end of 2013 – 14 and sheffield united midfielder elliott white ##house signed on a one @ - @ month loan . bro ##bbe ##l opened the
| 654 |
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scoring in the second minute of his home debut against mansfield town , although the away team went on to score twice to win 2 – 1 . york ' s run of four defeats ended following a 1 – 1 draw away to w ##y ##combe wanderers , in which mc ##gur ##k gave york the lead before the home team level ##led through dean morgan . taft was sent back to leicester after he fell behind mc ##gur ##k , par ##slow and smith in the peck ##ing order for a central defensive berth . york achieved their first win since the opening day of the season after beating portsmouth 4 – 2 at home , with fletcher ( 2 ) , montrose and
| 654 |
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jarvis scoring . defender luke o ' neill was signed from burnley on a 28 @ - @ day emergency loan . he made his debut in york ' s 3 – 0 win away at tor ##quay , which was the team ' s first successive win of the season . york were knocked out of the football league trophy in the second round after being beaten 3 – 0 at home by league one team rotherham united , before their winning streak in the league was ended with a 3 – 0 defeat away to newport county . york drew 2 – 2 away to chesterfield , having taken a two @ - @ goal lead through o ' neill and jarvis , before
| 654 |
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the home team fought back through armand g ##nan ##du ##ille ##t and jay o ' shea . the team then hosted fleetwood town , and the visitors won 2 – 0 with goals scored in each half by gareth evans and jam ##ille matt . sc ##unt ##horpe united were beaten 4 – 1 at home to end york ' s three @ - @ match run without a win , with all the team ' s goals coming in the first half from carson , fletcher and bro ##bbe ##l ( 2 ) . bowman scored his first goals for york away to cheltenham town , as york twice fought back from behind to draw 2 – 2 . york drew 3 – 3
| 658 |
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away to bristol rovers to earn a first round replay in the fa cup , taking the lead through jarvis before eliot richards equal ##ised for the home team . carson scored a 30 yard volley to put york back in the lead , and after bristol rovers goals from matt ha ##rro ##ld and chris beard ##sley , fletcher scored an 86 ##th @ - @ minute equal ##iser for york . bowman scored with a header from an o ' neill cross to open the scoring at home to plymouth argyle , which was the first goal the visitors had conceded in 500 minutes of action . however , plymouth equal ##ised 11 minutes later through top ##e ob ##ade ##yi and the match
| 659 |
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finished a 1 – 1 draw . york were knocked out of the fa cup after losing 3 – 2 at home to bristol rovers in a first round replay ; the visitors were 3 – 0 up by 50 @ - @ minutes before fletcher pulled two back for york with a penalty and a long @ - @ range strike . defender keith lowe , of cheltenham , and goalkeeper nick pope , of charlton athletic , were signed on loan until january 2014 . they both played in york ' s first league defeat in four weeks , 2 – 1 away , to southend united . ke ##van hurst gave southend the lead early into the match and bowman equal ##ised for
| 654 |
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york with a low strike during the second half , before luke pro ##sser scored the winning goal for the home side in stop ##page time . with pope preferred in goal , ke ##tting ##s returned to blackpool on his own accord , although his loan agreement would stay in place until january 2014 . york then drew 0 – 0 away to more ##cam ##be . after pope was recalled from his loan by charlton , york signed wolverhampton wanderers goalkeeper aaron mcc ##are ##y on loan until january 2014 . mcc ##are ##y kept a clean sheet in york ' s 0 – 0 home draw with rochdale . cr ##ess ##well retired from playing as a result of an eye complaint and
| 654 |
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a knee injury . york drew 1 – 1 away to burton albion , with an own goal scored by shane cans ##dell @ - @ she ##rri ##ff giving york the lead in the 64 ##th @ - @ minute before the home team equal ##ised eight minutes later through billy ke ##e . atkinson was released after failing to force himself into the first team and signed for scarborough athletic , with whom he had been on loan . york drew 0 – 0 at home with second @ - @ placed oxford united , in which carson came closest to scoring with a volley that flashed across the face of the goal . this was followed by another draw after the match away
| 654 |
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to acc ##rington stanley finished 1 – 1 , with the home team equal ##ising 10 minutes after a fletcher penalty had given york the lead in the 35th @ - @ minute . striker sha ##q mcdonald , who had been released by peterborough united , was signed on a contract until the end of the season . york ' s last match of 2013 was a 2 – 1 defeat away at bury , a result that ended york ' s run of consecutive draws at five . the home team were 2 – 0 up by the 19th @ - @ minute , before michael co ##uls ##on scored york ' s goal in the 73 ##rd @ - @ minute . this
| 654 |
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result meant york would begin 2014 in 22nd @ - @ position in the table , only out of the relegation zone on goal difference . jarvis scored the only goal in york ' s first win since october 2013 , a 1 – 0 home victory over more ##cam ##be on new year ' s day . mcc ##are ##y was recalled by wolverhampton wanderers due to an injury to one of their goalkeeper ##s , while o ' neill was recalled by burnley to take part in their fa cup match . york achieved back @ - @ to @ - @ back wins for the first time since october 2013 after da ##gen ##ham & red ##bridge were beaten 3 – 1 at
| 628 |
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home , with bowman opening the scoring in the second half before fletcher scored twice . adam reed , who had a spell on loan with york in the previous season , was signed on a contract until the end of the season after parting company with burton . davies ' loan was extended , while bro ##bbe ##l and white ##house returned to their parent clubs . cheltenham club captain russell penn , a midfielder , was signed on a two @ - @ and @ - @ a @ - @ half @ - @ year contract for an undisclosed fee . lowe was subsequently signed permanently from cheltenham on a two @ - @ and @ - @ a @ - @ half
| 654 |
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@ - @ year contract for an undisclosed fee . having been allowed to leave the club on a free transfer , ashley chambers signed for conference premier club cambridge united . york achieved three successive wins for the first time in 2013 – 14 after beating northampton 2 – 0 away , with bowman and fletcher scoring in three @ - @ second half minutes . defender john mcc ##om ##be was signed on a two @ - @ and @ - @ a @ - @ half @ - @ year contract following his release from mansfield , before clay and jamal f ##y ##field left york by mutual consent . pope returned to york on loan from charlton for the remainder of the
| 655 |
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season . york ' s run of wins ended with a 0 – 0 draw at home to bristol rovers , before their first defeat of the year came after losing 2 – 0 away to hart ##le ##pool . preston winger will hay ##hurst , a republic of ireland under @ - @ 21 international , was signed on a one @ - @ month loan . york fell to a successive defeat for the first time since september 2013 after being beaten 2 – 0 at home by chesterfield . shortly after the match , smith left the club by mutual consent to pursue first @ - @ team football . fletcher scored a 90 ##th @ - @ minute winner for york away
| 654 |
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to fleetwood in a 2 – 1 win , a result that ended fleetwood ' s five @ - @ match unbeaten run . york then drew 0 – 0 at home to fellow mid @ - @ table team cheltenham , before beating plymouth 4 – 0 away with goals from fletcher , mcc ##om ##be ( 2 ) and carson as the team achieved successive away wins for the first time in 2013 – 14 . york went without scoring for a fourth consecutive home match after drawing 0 – 0 with southend . having worn the arm ##band since an injury to mc ##gur ##k , penn was appointed captain for the rest of the season , a position that had earlier been
| 659 |
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held by smith and par ##slow . york achieved their first home win in five matches after beating exeter 2 – 1 , with first half goals scored by mcc ##om ##be and co ##uls ##on . hay ##hurst ' s loan was extended to the end of the season , having impressed in his six appearances for the club . co ##uls ##on scored again with the only goal , a 41st @ - @ minute header , in york ' s 1 – 0 away win over afc wimbledon . bowman scored the only goal with a 32nd @ - @ minute penalty as york won 1 – 0 away against mansfield , in which fletcher missed the opportunity to extend the lead when
| 659 |
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his stop ##page time penalty was saved by alan marriott . york moved one place outside the play @ - @ offs with a 2 – 0 home win over w ##y ##combe , courtesy of a second bowman penalty in as many matches and a carson goal from the edge of the penalty area . co ##uls ##on scored york ' s only goal in a 1 – 0 away win over struggling portsmouth with a low volley in the fifth @ - @ minute ; this result meant york moved into the play @ - @ offs in seventh @ - @ place with eight fixtures remaining . striker calvin andrew , who had been released by mansfield in january 2014 , was signed
| 654 |
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on a contract for the remainder of the season . he made his debut as a substitute in york ' s 1 – 0 home win over bottom of the table tor ##quay , in which hay ##hurst scored the only goal in the 11th @ - @ minute with an 18 yard shot that def ##le ##cted off aaron down ##es . middlesbrough winger bro ##bbe ##l rejoined on loan until the end of the season , following an injury to carson . york ' s run of successive wins ended on six matches after a 0 – 0 home draw with burton , and this result saw york drop out of the play @ - @ offs in eighth @ - @ place .
| 654 |
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with the team recording six wins and one draw in march 2014 , including six clean sheets , worth ##ington was named league two manager of the month . pope made a number of saves as york held league leaders rochdale to a 0 – 0 away draw , with a point being enough to lift the team back into seventh @ - @ place . york were prevented from equal ##ling a club record of eight consecutive clean sheets when acc ##rington scored a stop ##page time equal ##iser in a 1 – 1 home draw , in which york had taken earlier taken the lead with a co ##uls ##on penalty . a 1 – 0 win away win over oxford , which was
| 654 |
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decided by a second half co ##uls ##on penalty , resulted in york moving one place above their opponents and back into seventh @ - @ place . york consolidated their place in a play @ - @ off position after beating bury 1 – 0 at home with a fifth @ - @ minute goal scored by lowe from a hay ##hurst corner . the result meant york opened up a five @ - @ point lead over eighth @ - @ placed oxford with two fixtures remaining . a place in the league two play @ - @ offs was secured following a 1 – 0 win over newport at home , in which co ##uls ##on scored the only goal in the 77
| 654 |
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##th @ - @ minute with a 25 yard free kick . pope earned a nomination for league two player of the month for april 2014 , having conceded only one goal in five matches in that period . the league season concluded with an away match against divisional runners @ - @ up sc ##unt ##horpe ; having gone two goals down york fought back to draw 2 – 2 with goals scored by bro ##bbe ##l and andrew . this result meant york finished the season in seventh @ - @ place in league two , and would thus play fourth @ - @ placed fleetwood in the play @ - @ off semi @ - @ final on the back of a 17
| 658 |
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"=",
"="
] | 1,479 |
@ - @ match unbeaten run . york lost 1 – 0 to fleetwood in the first leg at booth ##am crescent ; the goal came from former york player matt ##y blair in the 50th @ - @ minute , who scored from close range after anton ##i sar ##ce ##vic ' s shot was blocked on the line . a 0 – 0 draw away to fleetwood in the second leg meant york were eliminated 1 – 0 on aggregate , ending the prospect of a second promotion in three seasons . at an awards night held at york racecourse , o ##ye ##ban ##jo was voted club ##man of the year for 2013 – 14 . = = summary and aftermath = =
| 654 |
[
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] | 1,480 |
york mostly occupied the bottom half of the table before the turn of the year , and dropped as low as 23rd in september 2013 . during february 2014 the team broke into the top half of the table and with one match left were in sixth @ - @ place . york ' s defensive record was the third best in league two with 41 goals conceded , better ##ed only by southend ( 39 ) and chesterfield ( 40 ) . davies made the highest number of appearances over the season , appearing in 47 of york ' s 52 matches . fletcher was york ' s top scorer in the league and in all competitions , with 10 league goals and 13 in
| 658 |
[
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] | 1,481 |
total . he was the only player to reach double figures , and was followed by jarvis with nine goals . after the season ended york released tom allan , andrew , dickinson , mcdonald , pu ##ri and reed , while mc ##gur ##k retired from professional football . bowman and o ##ye ##ban ##jo left to sign for tor ##quay and crawley town respectively while co ##uls ##on signed a new contract with the club . york ' s summer signing ##s included goalkeeper jason moon ##ey from tran ##mere rovers , defenders fe ##mi ile ##san ##mi from da ##gen ##ham , marvin mccoy from w ##y ##combe and dave winfield from shrewsbury town , midfielder ##s lin ##don mei ##kle from mansfield
| 657 |
[
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"=",
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":",
"numbers",
"in"
] | 1,482 |
, anthony st ##rak ##er from southend and luke summer ##field from shrewsbury and striker jake hyde from barnet . = = match details = = league positions are sourced by stat ##to , while the remaining information is referenced individually . = = = football league two = = = = = = football league trophy = = = = = = football league two play @ - @ offs = = = = = transfers = = brackets around club names denote the player ' s contract with that club had expired before he joined york . brackets around club names denote the player joined that club after his york contract expired . = = appearances and goals = = source : numbers in
| 659 |
[
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] | 1,483 |
parentheses denote appearances as substitute . players with names struck through and marked left the club during the playing season . players with names in italics and marked * were on loan from another club for the whole of their season with york . players listed with no appearances have been in the match ##day squad but only as unused substitutes . key to positions : g ##k – goalkeeper ; d ##f – defender ; m ##f – midfielder ; f ##w – forward = anti ##mony = anti ##mony is a chemical element with symbol sb ( from latin : st ##ib ##ium ) and atomic number 51 . a lust ##rous gray metal ##loid , it is found in nature mainly as the
| 578 |
[
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"and",
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] | 1,484 |
sul ##fide mineral st ##ib ##ni ##te ( sb ##2 ##s ##3 ) . anti ##mony compounds have been known since ancient times and were used for cosmetics ; metallic anti ##mony was also known , but it was erroneously identified as lead upon its discovery . in the west , it was first isolated by van ##no ##cci ##o bi ##ring ##ucci ##o and described in 1540 , although in primitive cultures its powder has been used to cure eye ai ##lm ##ents , as also for eye shadow , since time im ##me ##mori ##al , and is often referred to by its arabic name , ko ##hl . for some time , china has been the largest producer of anti ##mony and its
| 569 |
[
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"and",
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"products",
"."
] | 1,485 |
compounds , with most production coming from the xi ##ku ##ang ##shan mine in hunan . the industrial methods to produce anti ##mony are roast ##ing and reduction using carbon or direct reduction of st ##ib ##ni ##te with iron . the largest applications for metallic anti ##mony are as alloy ##ing material for lead and tin and for lead anti ##mony plates in lead – acid batteries . alloy ##ing lead and tin with anti ##mony improves the properties of the alloys which are used in sold ##ers , bullets and plain bearings . anti ##mony compounds are prominent additive ##s for ch ##lor ##ine and bro ##mine @ - @ containing fire re ##tar ##dant ##s found in many commercial and domestic products .
| 568 |
[
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"of",
"3"
] | 1,486 |
an emerging application is the use of anti ##mony in micro ##ele ##ct ##ron ##ics . = = characteristics = = anti ##mony is in the nitrogen group ( group 15 ) and has an electron ##ega ##tiv ##ity of 2 @ . @ 05 . as expected from periodic trends , it is more electron ##ega ##tive than tin or bis ##mut ##h , and less electron ##ega ##tive than tell ##uri ##um or arsenic . anti ##mony is stable in air at room temperature , but reacts with oxygen if heated , to form anti ##mony trio ##xide , sb ##2 ##o ##3 . anti ##mony is a silvery , lust ##rous gray metal ##loid that has a mo ##hs scale hardness of 3
| 568 |
[
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"of",
"arsenic",
".",
"a"
] | 1,487 |
. thus pure anti ##mony is too soft to make hard objects ; coins made of anti ##mony were issued in china ' s gui ##zhou province in 1931 , but because of their rapid wear , their mint ##ing was discontinued . anti ##mony is resistant to attack by acids . four all ##ot ##rop ##es of anti ##mony are known : a stable metallic form and three meta ##sta ##ble forms ( explosive , black and yellow ) . elemental anti ##mony is a brittle , silver @ - @ white shiny metal ##loid . when slowly cooled , molten anti ##mony crystal ##li ##zes in a tri ##gonal cell , iso ##morphic with the gray all ##ot ##rop ##e of arsenic . a
| 569 |
[
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"##ot",
"##rop",
"##e"
] | 1,488 |
rare explosive form of anti ##mony can be formed from the electro ##lysis of anti ##mony tri ##ch ##lor ##ide . when scratched with a sharp implement , an ex ##oth ##er ##mic reaction occurs and white fu ##mes are given off as metallic anti ##mony is formed ; when rubbed with a pest ##le in a mortar , a strong det ##ona ##tion occurs . black anti ##mony is formed upon rapid cooling of vapor derived from metallic anti ##mony . it has the same crystal structure as red phosphorus and black arsenic , it ox ##idi ##zes in air and may ign ##ite spontaneously . at 100 ° c , it gradually transforms into the stable form . the yellow all ##ot ##rop ##e
| 569 |
[
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] | 1,489 |
of anti ##mony is the most unstable . it has only been generated by oxidation of st ##ib ##ine ( sb ##h ##3 ) at − 90 ° c . above this temperature and in ambient light , this meta ##sta ##ble all ##ot ##rop ##e transforms into the more stable black all ##ot ##rop ##e . elemental anti ##mony adopt ##s a layered structure ( space group r ##3 ##m no . 166 ) in which layers consist of fused ru ##ffled six @ - @ member ##ed rings . the nearest and next @ - @ nearest neighbors form an irregular oct ##ah ##ed ##ral complex , with the three atoms in the same double layer being slightly closer than the three atoms in
| 569 |
[
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",",
"29",
"meta",
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"##ble",
"states",
"have",
"been",
"characterized",
"."
] | 1,490 |
the next . this relatively close packing leads to a high density of 6 @ . @ 69 ##7 g / cm ##3 , but the weak bonding between the layers leads to the low hardness and brittle ##ness of anti ##mony . anti ##mony has two stable isotope ##s : 121 ##sb with a natural abundance of 57 @ . @ 36 % and 123 ##sb with a natural abundance of 42 @ . @ 64 % . it also has 35 radio ##iso ##top ##es , of which the longest @ - @ lived is 125 ##sb with a half @ - @ life of 2 @ . @ 75 years . in addition , 29 meta ##sta ##ble states have been characterized .
| 569 |
[
"the",
"most",
"stable",
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"120",
"##m",
"##1",
"##sb",
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",",
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",",
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".",
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"'",
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".",
"@",
"5",
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",",
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".",
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".",
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",",
"it",
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"found",
"in"
] | 1,491 |
the most stable of these is 120 ##m ##1 ##sb with a half @ - @ life of 5 @ . @ 76 days . isotope ##s that are lighter than the stable 123 ##sb tend to decay by β + decay , and those that are heavier tend to decay by β − decay , with some exceptions . the abundance of anti ##mony in the earth ' s crust is estimated at 0 @ . @ 2 to 0 @ . @ 5 parts per million , comparable to tha ##lli ##um at 0 @ . @ 5 parts per million and silver at 0 @ . @ 07 pp ##m . even though this element is not abundant , it is found in
| 577 |
[
"over",
"100",
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"species",
".",
"anti",
"##mony",
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".",
"g",
".",
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"=",
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":",
"sb",
"(",
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".",
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"=",
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"=",
"=",
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"##mony",
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"6",
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"##mony",
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"air",
".",
"in",
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"gas",
"phase",
",",
"this",
"compound",
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"as",
"sb"
] | 1,492 |
over 100 mineral species . anti ##mony is sometimes found native ##ly ( e . g . on anti ##mony peak ) , but more frequently it is found in the sul ##fide st ##ib ##ni ##te ( sb ##2 ##s ##3 ) which is the predominant ore mineral . = = compounds = = anti ##mony compounds are often classified according to their oxidation state : sb ( iii ) and sb ( v ) . the + 5 oxidation state is more stable . = = = oxide ##s and hydro ##xide ##s = = = anti ##mony trio ##xide ( sb 6 ) is formed when anti ##mony is burnt in air . in the gas phase , this compound exists as sb
| 568 |
[
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"but",
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"##ing",
".",
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",",
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",",
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"##mon",
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"(",
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",",
"but",
"the",
"con",
"##ju",
"##gate",
"base",
"sodium"
] | 1,493 |
6 , but it polymer ##izes upon conde ##ns ##ing . anti ##mony pen ##to ##xide ( sb 10 ) can only be formed by oxidation by concentrated ni ##tric acid . anti ##mony also forms a mixed @ - @ vale ##nce oxide , anti ##mony te ##tro ##xide ( sb 4 ) , which features both sb ( iii ) and sb ( v ) . unlike oxide ##s of phosphorus and arsenic , these various oxide ##s are amp ##hot ##eric , do not form well @ - @ defined ox ##oa ##ci ##ds and react with acids to form anti ##mony salts . anti ##mon ##ous acid sb ( oh ) 3 is unknown , but the con ##ju ##gate base sodium
| 568 |
[
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"##sb",
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",",
"and",
"bo",
"##ula",
"##nger",
"##ite",
".",
"anti",
"##mony"
] | 1,494 |
anti ##mon ##ite ( [ na 3 ##sb ##o 4 ) forms upon fu ##sing sodium oxide and sb 6 . transition metal anti ##mon ##ites are also known . anti ##mon ##ic acid exists only as the hydra ##te hs ##b ( oh ) 6 , forming salts containing the anti ##mona ##te an ##ion sb ( oh ) − 6 . de ##hy ##dra ##ting metal salts containing this an ##ion yields mixed oxide ##s . many anti ##mony ore ##s are sul ##fide ##s , including st ##ib ##ni ##te ( sb 3 ) , p ##yra ##rgy ##rite ( ag 3 ##sb ##s 3 ) , z ##ink ##eni ##te , jameson ##ite , and bo ##ula ##nger ##ite . anti ##mony
| 568 |
[
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"##f",
"3",
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"conductor",
".",
"the",
"tri"
] | 1,495 |
pen ##tas ##ulf ##ide is non @ - @ st ##oic ##hi ##ometric and features anti ##mony in the + 3 oxidation state and s @ - @ s bonds . several th ##io ##ant ##imo ##ni ##des are known , such as [ sb anti ##mony forms two series of hal ##ides : sb ##x 5 . the tri ##hal ##ides sb ##f 3 are all molecular compounds having tri ##gonal pyramid ##al molecular geometry . the tri ##fl ##uo ##ride sb ##f 3 is prepared by the reaction of sb it is lewis acidic and readily accepts flu ##ori ##de ions to form the complex an ##ions sb ##f − 5 . molten sb ##f 3 is a weak electrical conductor . the tri
| 568 |
[
"##ch",
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"form",
"ox",
"##oa",
"##nti",
"##mony",
"##l"
] | 1,496 |
##ch ##lor ##ide sb ##cl 3 is prepared by di ##sso ##lving sb 3 in hydro ##ch ##lor ##ic acid : the pen ##ta ##hal ##ides sb ##f 5 have tri ##gonal bi ##py ##ram ##idal molecular geometry in the gas phase , but in the liquid phase , sb ##f 5 is polymer ##ic , whereas sb ##cl 5 is mono ##meric . sb ##f 5 is a powerful lewis acid used to make the super ##ac ##id flu ##oro ##ant ##imo ##nic acid ( " h ##2 ##sb ##f ##7 " ) . ox ##y ##hal ##ides are more common for anti ##mony than arsenic and phosphorus . anti ##mony trio ##xide dissolve ##s in concentrated acid to form ox ##oa ##nti ##mony ##l
| 565 |
[
"compounds",
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"##oc",
"##l",
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"##ine",
",",
"sb",
"##h",
"st",
"##ib",
"##ine",
"can",
"also",
"be"
] | 1,497 |
compounds such as sb ##oc ##l and ( sb ##o ) = = = anti ##mon ##ides , h ##yd ##ride ##s , and organ ##oa ##nti ##mony compounds = = = compounds in this class generally are described as derivatives of sb ##3 − . anti ##mony forms anti ##mon ##ides with metals , such as ind ##ium anti ##mon ##ide ( ins ##b ) and silver anti ##mon ##ide ( ag 3 ##sb ) . the al ##kali metal and zinc anti ##mon ##ides , such as na ##3 ##sb and z ##n ##3 ##sb ##2 , are more reactive . treating these anti ##mon ##ides with acid produces the unstable gas st ##ib ##ine , sb ##h st ##ib ##ine can also be
| 568 |
[
"produced",
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"##3",
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"##ride",
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",",
"an",
"##ions",
",",
"and",
"cat"
] | 1,498 |
produced by treating sb ##3 + salts with h ##yd ##ride re ##age ##nts such as sodium bo ##ro ##hy ##dr ##ide . st ##ib ##ine deco ##mp ##oses spontaneously at room temperature . because st ##ib ##ine has a positive heat of formation , it is the ##rm ##od ##yna ##mic ##ally unstable and thus anti ##mony does not react with hydrogen directly . organ ##oa ##nti ##mony compounds are typically prepared by al ##ky ##lation of anti ##mony hal ##ides with gr ##ign ##ard re ##age ##nts . a large variety of compounds are known with both sb ( iii ) and sb ( v ) centers , including mixed ch ##lor ##o @ - @ organic derivatives , an ##ions , and cat
| 568 |
[
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] | 1,499 |
##ions . examples include sb ( c ##6 ##h ##5 ) 3 ( trip ##hen ##yl ##sti ##bine ) , sb ##2 ( c ##6 ##h ##5 ) 4 ( with an sb @ - @ sb bond ) , and cyclic [ sb ( c ##6 ##h ##5 ) ] n . pen ##ta ##co ##ord ##inated organ ##oa ##nti ##mony compounds are common , examples being sb ( c ##6 ##h ##5 ) 5 and several related hal ##ides . anti ##mony ( iii ) sul ##fide , sb ##2 ##s ##3 , was recognized in pre ##dy ##nas ##tic egypt as an eye cosmetic ( ko ##hl ) as early as about 310 ##0 bc , when the cosmetic palette was invented .
| 83 |
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