On the definition of pseudoentropy $\mathbf{Definition.}$ A random variable $X$ has pseudoentropy $k$ if it is computationally indistinguishable from a random variable $Y$ with $H(Y) = k$, where $H(Y)$ is the Shannon entropy of $Y$.

By this definition, can we say that any random variable has pseudoentropy equals to its Shannon entropy, just because it is computationally indistinguishable from itself? The caveat here is whether or not the definition of computational indistinguishability is still valid when there is only one random variable, not two.
Yes, we can always say that $X$ has pseudoentropy at least $H(X)$. You can take $Y$ to be a completely separate, independent random variable that has the same distribution as $X$. Then $X$ and $Y$ are computationally indistinguishable (indeed they are "completely" indistinguishable): $\Pr[A(X) = 1] = \Pr[A(Y) = 1]$ for all algorithms $A$.

Instead of thinking of psuedoentropy as a property of a random variable, maybe it is more helpful to think of it as a property of a distribution. Not a big difference but emphasizes that, for instance, $X$ and $Y$ are never correlated in the definition.