Discovery of a peculiar DQ white dwarf
  We report the discovery of a new carbon rich white dwarf that was identified during a proper motion survey for cool white dwarfs based on photographic material used for the construction of the Guide Star Catalog II. Its large proper motion (0.48 arcsec/yr) and faint apparent magnitude (V = 18.7) suggest a nearby object of low luminosity. A low-resolution spectrum taken with the William Herschel Telescope clearly shows strong C2 Deslandres-d'Azambuja and Swan bands, which identify the star as a DQ white dwarf. The strength of the Deslandres-d'Azambuja bands and the depression of the continuum in the Swan-band region are signs of enhanced carbon abundance for the given Teff. Comparison of our spectrophotometric data to published synthetic spectra suggests 6000 K < Teff < 8000 K although further analysis with specialized synthetic models appear necessary to derive both Teff and chemical composition. Finally, the range of spatial velocity estimated for this object makes it a likely member of the halo or thick disk population. 
D. Carollo, S.T. Hodgkin, A. Spagna, R.L. Smart, M.G. Lattanzi, B.J.   McLean, D.J. Pinfield