Correlation of energy and free energy for the thermal Casimir force   between real metals
  The energy of fluctuating electromagnetic field is investigated for the thermal Casimir force acting between parallel plates made of real metal. It is proved that for nondissipative media with temperature independent dielectric permittivity the energy at nonzero temperature comprises of the (renormalized) energies of the zero-point and thermal photons. In this manner photons can be considered as collective elementary excitations of the matter of plates and electromagnetic field. If the dielectric permittivity depends on temperature the energy contains additional terms proportional to the derivatives of dielectric permittivity with respect to temperature, and the quasiparticle interpretation of the fluctuating field is not possible. The correlation between energy and free energy is considered. Previous calculations of the Casimir energy in the framework of the Lifshitz formula at zero temperature and optical tabulated data supplemented by the Drude model at room temperature are analysed. It is demonstrated that this quantity is not a good approximation either for the free energy or the energy. A physical interpretation of this hybrid quantity is suggested. The contradictory results in the recent literature on whether the zero-frequency term of the Lifshitz formula for the perpendicular polarized modes has any effective contribution to the physical quantities are discussed. Four main approaches to the resolution of this problem are specified. The precise expressions for entropy of the fluctuating field between plates made of real metal are obtained, which helps to decide between the different approaches. The conclusion is that the Lifshitz formula supplemented by the plasma model and the surface impedance approach are best suited to describe the thermal Casimir force between real metals. 
V. B. Bezerra, G. L. Klimchitskaya, V. M. Mostepanenko