The second phase transition in the pyrochlore oxide Cd2Re2O7
  Evidence for another phase transition at 120 K in the metallic pyrochlore oxide Cd2Re2O7, following the structural transition at 200 K and followed by the superconducting transition at 1.0 K, is given through resistivity, magnetoresistance, specific heat, and X-ray diffraction measurements. The results indicate unique successive structural and electronic transitions occurring in the pyrochlore compound, revealing an interesting interplay between the crystal and electronic structures on the itinerant electron system in the pyrochlore lattice. 
Zenji Hiroi, Jun-Ichi Yamaura, Yuji Muraoka, and Masafumi Hanawa