Radiative charge transfer lifetime of the excited state of (NaCa)$^+$
  New experiments were proposed recently to investigate the regime of cold atomic and molecular ion-atom collision processes in a special hybrid neutral-atom--ion trap under high vacuum conditions. The collisional cooling of laser pre-cooled Ca$^+$ ions by ultracold Na atoms is being studied. Modeling this process requires knowledge of the radiative lifetime of the excited singlet A$^1\Sigma^+$ state of the (NaCa)$^+$ molecular system. We calculate the rate coefficient for radiative charge transfer using a semiclassical approach. The dipole radial matrix elements between the ground and the excited states, and the potential curves were calculated using Complete Active Space Self-Consistent field and M\"oller-Plesset second order perturbation theory (CASSCF/MP2) with an extended Gaussian basis, 6-311+G(3df). The semiclassical charge transfer rate coefficient was averaged over a thermal Maxwellian distribution. In addition we also present elastic collision cross sections and the spin-exchange cross section. The rate coefficient for charge transfer was found to be $2.3\times 10^{-16}$ cm$^3$/sec, while those for the elastic and spin-exchange cross sections were found to be several orders of magnitude higher ($1.1\times 10^{-8}$ cm$^3$/sec and $2.3\times 10^{-9}$ cm$^3$/sec, respectively). This confirms our assumption that the milli-Kelvin regime of collisional cooling of calcium ions by sodium atoms is favorable with the respect to low loss of calcium ions due to the charge transfer. 
Oleg P. Makarov, R. C\^ot\'e, H. Michels, W. W. Smith (Department of   Physics, University of Connecticut, Storrs, CT)