Note on Canonical Quantization and Unitary Equivalence in Field Theory
  The problem of defining and constructing representations of the Canonical Commutation Relations can be systematically approached via the technique of {\it algebraic quantization}. In particular, when the phase space of the system is linear and finite dimensional, the `vertical polarization' provides an unambiguous quantization. For infinite dimensional field theory systems, where the Stone-von Neumann theorem fails to be valid, even the simplest representation, the Schroedinger functional picture has some non-trivial subtleties. In this letter we consider the quantization of a real free scalar field --where the Fock quantization is well understood-- on an arbitrary background and show that the representation coming from the most natural application of the algebraic quantization approach is not, in general, unitary equivalent to the corresponding Schroedinger-Fock quantization. We comment on the possible implications of this result for field quantization. 
Alejandro Corichi, Jeronimo Cortez, Hernando Quevedo