Glass Transition in the Polaron Dynamics of CMR Manganites
  Neutron scattering measurements on a bilayer manganite near optimal doping show that the short-range polarons correlations are completely dynamic at high T, but then freeze upon cooling to a temperature T* 310 K. This glass transition suggests that the paramagnetic/insulating state arises from an inherent orbital frustration that inhibits the formation of a long range orbital- and charge-ordered state. Upon further cooling into the ferromagnetic-metallic state (Tc=114 K), where the polarons melt, the diffuse scattering quickly develops into a propagating, transverse optic phonon. 
D. N. Argyriou, J.W. Lynn, R. Osborn, B. Campbell, J. F. Mitchell, U.   Ruett, H. N. Bordallo, A. Wildes, C. D. Ling