startkde: run kbuildsycoca5
startkde: run kbuildsycoca5

Fixes #20776. At some point, the call to rebuild the sycoca database at startup
was removed, but it will not be rebuilt automatically because the timestamps in
the Nix store never change.

SymbiFlow/nixpkgs,NixOS/nixpkgs,NixOS/nixpkgs,NixOS/nixpkgs,SymbiFlow/nixpkgs,NixOS/nixpkgs,SymbiFlow/nixpkgs,SymbiFlow/nixpkgs,NixOS/nixpkgs,SymbiFlow/nixpkgs,SymbiFlow/nixpkgs,SymbiFlow/nixpkgs,NixOS/nixpkgs,SymbiFlow/nixpkgs,NixOS/nixpkgs,NixOS/nixpkgs,SymbiFlow/nixpkgs,SymbiFlow/nixpkgs,NixOS/nixpkgs,SymbiFlow/nixpkgs,NixOS/nixpkgs,SymbiFlow/nixpkgs,NixOS/nixpkgs,SymbiFlow/nixpkgs,NixOS/nixpkgs,NixOS/nixpkgs,NixOS/nixpkgs,NixOS/nixpkgs