Add PendingDeprecationWarning to internal requests methods
Add PendingDeprecationWarning to internal requests methods

This produces no output yet unless you explicitly turn on
warnings.  In a future release we'll have this emit a warning
by default.

I opted to put this in the high level `botocore.vendored.requests.*`
methods because that's the more common usage of requests and I wanted
better error messages.  Moving it to the `Session.request` method
would mean we couldn't give as helpful of an error message.

pplu/botocore,boto/botocore